One method that has become an exceedingly useful tool is dynamic kinetic resolution (DKR). [2][3] DKR utilizes a center of a particular molecule that can be easily epimerized so that the (R) and (S) …

Chemical Dynamic Kinetic Resolution: Ru(II) Reductions in Synthesis Without base, a classical KR is observed; choice of base is crucial for DKR.

Copper/Lipase-Cocatalyzed DKR of Atropisomeric Bisnaphthols Using a Neutral and Reliable Ligand L4 offers π* orbitals allowing additional metal-to-ligand d-π* back-donation to enhance...

May 2, 2026 · Chemoenzymatic dynamic kinetic resolution (DKR) offers a powerful bridge between chemocatalysis and biocatalysis for the preparation of chiral molecules.

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Jun 30, 2022 · Kinetic resolution (KR) and dynamic kinetic resolution (DKR) based on ketoreductases catalyzed reductions. For both KR and DKR, the racemic substrate was used as the start material, …

Nov 22, 2024 · Abstract Dynamic kinetic resolution (DKR) is a key method used to prepare optically pure compounds in 100 % theoretical yield starting from racemic substrates by combining the …

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Apr 17, 2025 · In this review, we summarize the development for the synthesis of optically active atropisomeric biaryls through a DKR or DyKAT route. Different racemization strategies have been …

This combination leads to a so called “dynamic kinetic resolution” (DKR), where the two enantiomers are in equilibrium with one another. The slow-reacting enantiomer will continuously be converted into the …